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Coal gas : ウィキペディア英語版
Coal gas

Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities.
Coal gas contains a variety of calorific gases including hydrogen, carbon monoxide, methane and volatile hydrocarbons together with small quantities of non-calorific gases such as carbon dioxide and nitrogen.
Prior to the development of natural gas supplies and transmission systems (during the 1940s and 1950s in the US and the late 1960s and 1970s in the UK), virtually all fuel and lighting gas used in both the United States and Great Britain was manufactured from coal. Gas was often supplied to households via a municipally owned piped distribution system.
Originally created as a by-product of the coking process, its use developed during the 19th and early 20th centuries tracking the industrial revolution and urbanization. By-products from the production process included coal tars and ammonia, which were important chemical feedstock for the dye and chemical industry with a wide range of artificial dyes being made from coal gas and coal tar. Facilities where the gas was produced were often known as a manufactured gas plant (MGP) or a gasworks.
The discovery of large reserves of natural gas in the North Sea off the UK coast during the early 1960s led to the expensive conversion or replacement of most of the nation's gas cookers and gas heaters, with the exception of Northern Ireland, from the late 1960s onwards.
The production process is distinct, both physically and chemically, from that used to create a range of gaseous fuels known variously as manufactured gas, syngas, hygas, Dowson gas, and producer gas. These gases are made by partial combustion of a wide variety of feed stocks in some mixture of air, oxygen, or steam, to reduce the latter to hydrogen and carbon dioxide although some destructive distillation may also occur.}&}&
==Manufacturing processes==
(詳細はcarbonization or gasification. Carbonization refers to the devolatilization of an organic feedstock to yield gas and char. Gasification is the process of subjecting a feedstock to chemical reactions that produce gas.〔Beychok, M.R., ''Process and environmentals technology for producing SNG and liquid fuels'', U.S, EPA report EPA-660/2-2-75-011, May 1975〕〔Beychok, M.R., ''Coal gasification and the phenolsolvan process'', American Chemical Society 168th National Meeting, Atlantic City, September 1974〕
The first process used was the carbonization and partial pyrolysis of coal. The off gases liberated in the high-temperature carbonization (coking) of coal in coke ovens were collected, scrubbed and used as fuel. Depending on the goal of the plant, the desired product was either a high quality coke for metallurgical use, with the gas being a side product or the production of a high quality gas with coke being the side product. Coke plants are typically associated with metallurgical facilities such as smelters, and blast furnaces, while gas works typically served urban areas.
A facility used to manufacture coal gas, carburetted water gas (CWG), and oil gas is today generally referred to as a manufactured gas plant (MGP).
In the early years of MGP operations, the goal of a utility gas works was to produce the greatest amount of illuminating gas. The illuminating power of a gas was related to amount of soot-forming hydrocarbons (“illuminants”) dissolved in it. These hydrocarbons gave the gas flame its characteristic bright yellow color. Gas works would typically use oily bituminous coals as feedstock. These coals would give off large amounts of volatile hydrocarbons into the coal gas, but would leave behind a crumbly, low-quality coke not suitable for metallurgical processes. Coal or coke oven gas typically had a calorific value between 10 and 20 MJ/m³ (250-550 Btu/ft3 (std)); with values around 20 MJ/m³ (550 Btu/ft3 (std)) being typical.
The advent of electric lighting forced utilities to search for other markets for manufactured gas. MGPs that once produced gas almost exclusively for lighting shifted their efforts towards supplying gas primarily for heating and cooking, and even refrigeration and cooling.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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